Synthesis, Structural Characterization, Spectral Analysis and Antimicrobial Activities of Schiff Base Ligands and Their Metal Complexes Derived From 3-Aldehydosalicylic Acid

basavaraj kalshetty

Authors

basavaraj kalshetty

OONO donor coordination Nitrogen Coumarine

Abstract

The synthesis of new Schiff base ligands formed by the condensation of 3-Aldehydosalicylic acid with equimolar quantities of 2-Amino-5-methyl pyridine, 4-Amino-5-phenyl-3-mercapto-[1,2,4] -Triazole, 4-Amino-3-methyl-5-mercapto-Triazole, 7-Amino-4-ethyl Coumarin forming 2-(5-methyl pyridine-2-yl amino)-methyl-2-hydroxy-Benzoic acid (Scheme 1), 3-[(3-phenyl-5-mercapto-[1,2,4] triazole-4-yl amino)-methyl] -2-hydroxy-Benzoic acid (Scheme 4), 3-[(3-methyl-5-mercapto-[1,2.4] triazoile-4-yl amino)-methyl]-2-hydroxy-Benzoic acid (Scheme 7), 3-[(4-Ethyl-Coumarin-7-yl amino)-methyl] -2hydroxy-Benzoic acid (Scheme 11).

Downloads

How to Cite

Synthesis, Structural Characterization, Spectral Analysis and Antimicrobial Activities of Schiff Base Ligands and Their Metal Complexes Derived From 3-Aldehydosalicylic Acid. (2013). Global Journal of Science Frontier Research, 13(B2), 31-39. https://journalofscience.org/index.php/GJSFR/article/view/750

Download Citation

References

Unknown Title. (1).

Roy Palmer (2004) Price, Laurence (fl. 1628-1675), ballad and chapbook writer. 1675.

H Unknown Title.

C-H) 3000 cm -1 '' √(-C=O) 1690 cm -1 '' √(-C=O) 1690 cm.

G Pannetier, A Mbomé, N Platzer (1971) Nouveaux complexes du rhodium(III) le malonate de malonato-triaquo-ammine-rhodium(III) [Rh(COO-CH2-COO)(H2O)3(NH3)]2(COO-CH2-COO) le succinate de succinato-triaquo-ammine-rhodium(III) [Rh(COO-CH2-CH2-COO)(H2O)3(NH3)]2(COO-CH2-CH2-COO). 23(4), 403-414.

Scheme9 -COO-) 1748 cm -1 '' √(-C=N) 1675 cm -1 '' √(-C=N) 1628 cm.

Darrell Burch (1985) Absorption by H2O in Narrow Windows between 3000 and 4200 CM(-1).. 1690-1691.

Scheme3 √(-COO-) 1749 cm -1 '' √(-C=N) 1628 cm -1 '' √(-C=N) 1620 cm -1 '' -M-S) 458 cm -1 '' √(-C=O) 1690 cm -1 '' √(-C=O) 1690 cm -1.

Ml Dimeric 101 o C OONS-donor 8 4.

Ml 2 Monomer 218 o C OO-donor 9.

M( Lh Monomer 230 o C OOS-donor 10. 2.

Ml(etoh Dimeric 98 o C OONS-donor 12. 2.

M( Lh Monomer 212 o C ON-donor 13. 2.

Ml(etoh Monomer 89 o C OON-donor 14 9.

Ml Unknown Title. 2.

C Oono-Donor √( M N) √( M Scheme4 √(-COOH) 3300 cm -1 Scheme11 √(-COOH) 3300 cm -1 '' √(-OH) 3149 cm -1 '' √(-OH) 3150 cm -1 '' √(-C=N) 1628 cm -1 '' √(-C=N) 1628 cm -1 '' √(-C-H) 3000 cm -1 '' √(-C-H) 3000 cm -1 √(-C=O) 1690 cm -1 Scheme5 √(-COO-) 1748 cm -1 Scheme12 √(-COOH) 3300 cm -1 '' √(-C=N) 1628 cm -1 '' √(-M-N) 578 cm -1 '' √(-C=O) 1690 cm -1 '' √(-C=N) 1628 cm -1 '' √(-C-H) 3000 cm -1 '' √(-C-H) 3000 cm -1 '' √(-C=O) 1690 cm -1 Scheme6 √(-COO-) 1748 cm -1 Scheme13 √(-COO-) 1748 cm -1 '' √(-C=N) 1628 cm -1 '' √(-C=N) 1628 cm -1 '' √(-C=O) 1690 cm -1 '' √(-C=O) 1690 cm -1 '' √(-M-S) 458 cm -1 '' √(-M-N) 578 cm -1 '' √(-C-H) 3000 cm -1 Scheme7 √(-COOH) 3300 cm -1 Scheme14 √(-COO-) 1748 cm -1 '' √(-OH) 3150 cm -1 '' √(-C=N) 1628 cm -1 '' √(-C=N) 1675 cm -1 '' √(-C=O) 1690 cm -1 '' √(-C-H) 3000 cm -1 '' √(-M-N) 578 cm -1 '' √(-C=O) 1690 cm -1 '' √(-C-H) 3000 cm -1 REFERENCES RÉFÉRENCES REFERENCIAS.

J Pandya, K Ganatra (2010) Unknown Title. 5, 221.

J Zhao, B Zhao, J Liu, W Xu, Z Wang (2001) Unknown Title. 57, 149.

S Abdel-Latif, H Hassib, Y Issa (2007) Studies on some salicylaldehyde Schiff base derivatives and their complexes with Cr(III), Mn(II), Fe(III), Ni(II) and Cu(II). 67(3-4), 950-957.

R Ramesh, S Maheswaran (2003) Synthesis, spectra, dioxygen affinity and antifungal activity of Ru(III) Schiff base complexes. 96(4), 457-462.

Z Cimerman, N Galic, B Bosner (1997) Unknown Title. 343, 145.

Zvjezdana Cimerman, Snezana Miljanic, Nives Galic (2000) ChemInform Abstract: Schiff Bases Derived from Aminopyridines as Spectrofluorimetric Analytical Reagents.. 31(19), 81.

D Hamilton, R Drage, A Zombecki (1987) Unknown Title. 109, 374.

D Chem, A Matel (1987) Unknown Title. 26, 1026.

J Costamagna, J Vargas, R Latorre, A Alvaararade, G Mena (1992) tridentate OON-donor ligand forming the monometallic complex compound of the type [ML 2 ]: M= Zn, Cd (Scheme 3). At the same pH-7 the ligand formed OOSdonor monometallic complex compound of the type [M (LH) 2 ]: M= Zn,Cd (Scheme 9). 13.

B Kalshetty, S Gaonkar, Ramesh Gani, M Kalashetti (2012) ASSESSMENT AND TOXICITY OF FLUORIDE FROM GROUND WATER SOURCES IN AND AROUND BAGALKOT DISTRICT, KARNATAKA, INDIA. 4(5), 246-249.

A Matel (1987) Unknown Title. 26, 1026.

J Costamagna, J Vargas, R Latorre, A Alvarado, G Mena (1992) Coordination compounds of copper, nickel and iron with Schiff bases derived from hydroxynaphthaldehydes and salicylaldehydes. 119, 67-88.

(null) PART IV: Conclusions.

P Ronad, R Hunshi, D Satayanarayana, V Maddi (2008) Unknown Title. 341, 696.

Yogesh Tyagi, Ajit Kumar, Hanumantharao Raj, Parag Vohra, Garima Gupta, Ranju Kumari, Pankaj Kumar, Rajinder Gupta (2005) Synthesis of novel amino and acetyl amino-4-methylcoumarins and evaluation of their antioxidant activity. 40(4), 413-420.

Santiago Vilar, Elias Quezada, Lourdes Santana, Eugenio Uriarte, Matilde Yanez, Nuria Fraiz, Carlos Alcaide, Ernesto Cano, Francisco Orallo (2006) Design, Synthesis, and Vasorelaxant and Platelet Antiaggregatory Activities of Coumarin-Resveratrol Hybrids.. 37(16), 257.

Jolanta Nawrot-Modranka, Ewa Nawrot, Julita Graczyk (2006) Corrigendum to "In vivo antitumor, in vitro antibacterial activity and alkylating properties of phosphorohydrazine derivatives of coumarin and chromone" [Eur J Med Chem 41 (11) (2006) 1301-1309]. 42(6), 891.

Donglei Yu, Madoka Suzuki, Lan Xie, Susan Morris‐natschke, Kuo‐hsiung Lee (2003) Recent progress in the development of coumarin derivatives as potent anti‐HIV agents. 23(3), 322-345.

N Korli, A Kocabalkanli, A Gursoy, O Ates (2002) Unknown Title. 57, 589.

Kalagouda Gudasi, Manjula Patil, Ramesh Vadavi (2008) Synthesis, characterization of copper(II), cobalt(II), nickel(II), zinc(II) and cadmium(II) complexes of [7-hydroxy-4-methyl-8-coumarinyl]glycine and a comparitive study of their microbial activities. 43(11), 2436-2441.

Ken Coleman, Drugdiscov (2004) Recent advances in the treatment of Gram-positive infections. 1(4), 455-460.

C Sexena, R Singh (1992) Unknown Title. 22, 1061.

J Duff, E Bills (1932) 273. Reactions between hexamethylenetetramine and phenolic compounds. Part I. A new method for the preparation of 3- and 5-aldehydosalicylic acids. 1987.

D Kumar, P Gupta, A Syamal (2002) Unknown Title. 2494.

Sailendra Poddar (1963) Complex Compounds of Schiff's bases of 3‐aldehydo‐salicylic acid. 322(5-6), 326-336.

J, K Nag, S Pal, C Sinha (2005) Unknown Title. 30, 523.

Kiran Singh, D Singh, Manjeet Singh Barwa, Parikshit Tyagi, Yasmin Mirza (2006) Some bivalent metal complexes of Schiff bases containing N and S donor atoms. 21(6), 749-755.

C Sexena, R Singh (1994) Phosphorus, Sulphur. 97, 17.

Savita Belwal, R Singh (1998) Bioactive versatile azomethine complexes of organotin(IV) and organosilicon(IV). 12(1), 39-46.

I Grandberg, L Denisov, O Popova (1987) 7-Aminocoumarins (Review). 23(2), 117-142.

V Joshep, J Pandya, K Vivek, R Gupta, Jadeja (2012) Unknown Title. 89, 1455-1464.

B Kalshetty, T Giraddi, R Pattar, Ramesh Gani, M Kalashetti (2012) Unknown Title. 2(3), 1206-1217.

Frank. Smith, Lian Khoo, Ngoh Goh, Rosemary Hynes, George Eng (1996) The synthesis, and molecular and crystal structure of diphenyl(2-oxidonaphthylmethyl-iminoacetato)tin(IV). 74(11), 2041-2047.