Triarylantimony(V) Dicarboxylates: Synthesis, Characterisation and Reactions
Keywords:
Triarylantimony, Dicarboxylates, Hydrolytic stability, IR spectra, NMR spectra, Metathesis, Chelate
Abstract
A series of new triarylantimony V dicarboxylates of the general formula Ar3SbL2 where Ar C6H5and L C6H5CONHCH2COO C6H2 OH 3COO C6H5COO C6H5C2H2COO C6H4 OH COO C6H5 2 OH C COO have been prepared by the reaction of triarylantimony V dichloride and a carboxylic acid in the presence of triethylamine as well as the metathesis of sodium or silver salt of the carboxylic acid andtriarylantimony V dichloride The newly synthesized compounds have been characterized by conventional methods A tentative trigonalbipyramidal structure is suggested in which OCOR group occupy axial position and the three organic groups are situated at the equatorial position The melting points of compounds did not change even after prolong stirring with water at room temperature for several hours indicating their hydrolytic stability
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Published
2015-03-15
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