Synthesis, Spectroscopic, Thermodynamic and Biological Activity Studies of Schiff Base and Metal Complexes Derived From 2-[ 1H-Pyrrol-2-Ylimino Methyl]- 5-Phenyl-1,3,4- Oxadiazole
schiff base, microwave synthesis, thermodynamic parameters, biological activity
Abstract
New metal complexes of the ligand (HL) 2-[1H-Pyrrol-2-ylimino methyl]-5-phenyl-1, 3,4-oxadiazol with the metal ions Co(II), Ni(II) and Cu(II), were prepared in alcoholic medium. The Schiff bases were condensed by using [Pyrrolcarboxaldehyde] with[2-amino-5-(phenyl-1, 3,4-oxadiazole] in alcoholice medium. As the Schiff baseprepared was tridentate ligand, it was used for forming complexes with Co+2, Ni+2, Cu +2 and Zn+2 ions of type M (HL)2. All the synthesized Schiff base and their metal complexes were characterized by FTIR Spectroscopy, Electronic Spectroscopy, Elemental Analysis,
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M Farah, A Pilotti (2006) Unknown Title. 11(3-4), 165-174.
B Waston, J Tierney, P Lidstrom (2002) Unknown Title. 6, 373-380.
Mazaahir Kidwai,, Rajesh Kumar,, Yogesh Goel, (1997) MICROWAVE-ASSISTED SYNTHESIS OF NOVEL BIOLOGICALLY ACTIVE ORGANOMERCURIALS. 20(6), 367-372.
K Khan, M Rani, S Haider (2004) Unknown Title. 1, 151.
Yousif Ameer, A Sabbah, A (2004) Complexes of 2-Amino-5-(p-propoxyphenyl)-1, 3, 4-oxadiazole With Some Metal Ions. 2, 65-69.
G Abbiati, A Arcadi, O Attanasi, De Crescentini, L Rossi, E Johnsoa, Wilcox (1969) Unknown Title. 219.
N Chudgar, S Shah, R Vora (1989) Mesogenic Semicarbazones and Amino Oxadiazoles-I. 172(1), 51-56.
R Sliverstien, G Bassler, T Morrill (2005) Spectrometric Identification of Organic Compounds. 7th addition.
Nakamotok (1963) Infrared Spectra of Inorganic Coordination Compounds. By Kazuo Nakamoto. John Wiley & Sons Inc.. 400 Park Ave. South, New York 16, N. Y. xii + 328pp. 15 X 23cm. Price $9.50.. 52(8), 818.
D Adans (1967) Metal-Ligand and related Vibration. 33, 310.
S M F Rahman, Ahmad Haq, M (2009) Tris-(salicylaldehyde)-complexes"JInorgNuclChem. 4(4), 229-234.
K Sahoo, P Das, S Nayak (1973) Synthesis and Characterization of Some Cobalt. III, 1011.
R Sarika, R Amit, B Gaurav, S Anand (2003) Synthesis and characterization of transition metal complexes with N, O-chelating Hydrazone Schiff base ligand", American-Eurasian Complexes Containing Heterocyclic Nitrogen Donor Ligands. 57(2), 91-96.
Manish Srivastava, Deepak Singh, Aashishsinghkushwah, P (2010) Unknown Title. 04, 20-24.
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