Leave-Intercalation Theory and Conductive Mechanism during Charge-Discharge Process for Secondary Battery
hydrogen-nickel battery; lithium-ion battery, phase transition theory, x-ray diffraction, de-intercalation theory, conductive mechanism
Abstract
The source of conductive ions in the charge and discharge process of AB 5 / β -Ni(OH) 2 , 2H-graphite/ LiMeO 2 and 2H-graphite/LiFePO 4 batteries is thought to be provided by the phase transition of positive active materials, so it is called phase transition theory. Through the detailed study of the charge and discharge processes of AB 5 / β -Ni(OH) 2 , 2H-graphite/ Li(Ni 1/3 Co 1/3 Mn 1/3 )O 2 and 2H-graphite/LiFePO 4 , it is found that the source of conductive ions is the deintercalation of H (nickel-hydrogen battery) and Li (lithium-ion battery) in positive and negative active materials, and the de-intercalation theory is proposed. On this basis, the conductive mechanisms of these three types of batteries are clarified: The directional migration and movement of conductive ions under the action of electric field.
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H Bode, K Dehmelt, J Witte (1966) Zur kenntnis der nickelhydroxidelektrode-I.Über das nickel (II)-hydroxidhydrat. 11(8), 1079-1087.
A Shukla, S Venugopalan, Hariprakash (2001) Nickel-based rechargeable batteries. 100, 125-148.
Li Guoxin, ; Chief (2007) introduction to New Chemical Power supply Technology. 172, 218.
Xing Zhengliang, Li Guoxun, Wang Chaoqun, Xiao Jinsheng (1999) XRD in situ observation of nickel electrode during charge and discharge. 23(2), 140-142.
Wang Chaoqun, Xing Zhengliang, Wang Ning, Li Guoxun, Wu Burong (1999) quantitative Phase Analysis of-NiOOH on Nickel electrode.
Ulrik Palmqvist, Lars Eriksson, Javier Garcı́a-Garcı́a, Nina Simic, Elisabet Ahlberg, Rune Sjövall (2001) On the misuse of the crystal structure model of the Ni electrode material. 99(1-2), 15-25.
Li Yuxia, Yang Chuanzheng, Lou Yuwan, Xia Baojia (2009) study on the physical mechanism of conductivity in the charge-discharge process of MH/Ni batteries. 67(9), 901-909.
Qinpei Lou Yuwan, Yang Chuanzheng, Xia Baojia (2006) a new method and calculation program for separating multiple broadening effects of X-ray diffraction lines. 55(3), 1325-1335.
Yang Chuanzheng, Zhang Jian (2008) advances in the study of microstructure of nanomaterials by Xray diffraction. 28(3), 313.
Lou Yu-Wan, Yang Chuan-Zheng, Zhang Xi-Gui (2006) Comparative study on microstructure of β -Ni(OH) 2 as cathode material for Ni-MH battery. 49(3), 297-312.
Huilong Zhu, Dawei Bi, Zhiyuan Hu, Xin Xie, Zhengxuan Zhang, Shichang Zou (2019) THE DEGRADATION INDUCED BY HOT-CARRIER INJECTION IN 130-NM PARTIALLY DEPLETED SOI PMOSFETS FABRICATED ON MODIFIED WAFER. 43-46.
Yang Chuanzheng, Lou Yu-Wan, Li Yuxia, Xia Baojia (2009) some advances in the study of the relationship between the performance of Ni/MH batteries with fine structure of electrode active materials. 29(1), 126.
Jan Reimers, J Dahn (1992) Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in Li x CoO2. 139(8), 2091-2097.
G Amatucci, J Tarascon, L C Klein (1996) CoO2, The End Member of the Li x CoO2 Solid Solution. 143(3), 1114-1123.
X Yang, X Sun, J Mcbreen (2000) Unknown Title. 2, 100-103.
X Sun, X Yang, J Mcbreen, Y Gao, M Yakovleva, X Xing, M Daroux (2001) New phases and phase transitions observed in over-charged states of LiCoO2-based cathode materials☆. 97-98, 274-276.
Li Jia, Yang Chuanzheng, Zhang Jian, Zhang Xigui, Xia Baojia (2010) Unknown Title. 68(7), 646-652.
Li Jia, Yang Chuanzheng, Zhang Jian, Xia Baojia (2009) Unknown Title. 58(9), 6573-6581.
A Padhi, K Nanjundaswamy, J Goodenough (1997) Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium Batteries. 144(4), 1188-1194.
V Srinivasan, J Newman Discharge model for the lithium iron-phosphate-electrode，. 151(10), 1517-A1529.
Atsuo Yamada, Hiroshi Koizumi, Noriyuki Sonoyama, Ryoji Kanno (2005) Phase Change in Li[sub x]FePO[sub 4]. 8(8), A409.
J Dodd, R Yazami, B Fultz (2006) Phase diagram of LixFePO4. 9(3), A151-A155.
Qian Wang, Jian Zhang, Chuan-Zheng Yang, Bao-Xia，j Electrochem, Soc, Li Liu Haohan, Zhang Jia, Yang Jian, Xia Chuanzheng, Baojia (2010) Phase transition Nature and Conductive Mechanism of Graphite / LiFePO4 Battery during charge and discharge.
D Destenay (1948) Rowley, Rev. Harold Henry, (24 March 1890-4 Oct. 1969), Foreign mem., Roy. Flemish Acad.; Mem., Roy. Soc. of Letters of Lund; Hon. Mem., Soc. of Biblical Literature (USA); Hon. Fell., Sch. of Oriental and Afr. Studies, London. 10(4), 28.
A Wilson (1950) Deutsche Chemikalien‐und Werkstoffpreise. 22(13-14), 319-319.
W Eventoff, Martin Peacor, D (1972) Unknown Title. 57, 314.
Zhang Jian, Wang Qian, Xie Xiaohua, Yang Chuanzheng, Xia Baojia (2012) strain Analysis and Conductive Mechanism of Lithium Ion Battery during charge and discharge. 1(1), 72-86.
Jiang Chuanhai, Yang Chuanzheng (2013) Internal stress diffraction Analysis, Chapter 14 stress Analysis and Conductive Mechanism of Green Secondary Battery Beijing. 11.
Yang Chuanzheng, Lou Yuwan, Zhang Jian, Xie Xiaohua, Xia Baojia (2015) material characterization and electrode process Mechanism of Green Secondary Battery. 9.
Yang Chuanzheng (2020) study on Kinetic characteristics and Mechanism of hydrogen absorption/ Desorption of Alloy hydrogen Storage Materials. (12), 1002-1026.
Yang Chuan-Zheng, Lou Yu-Wan，zhang Jian, Xie Xiao-Hua, Xia Bao, -Jia (2015) 《Characterization of Material and Mechanism of electrode process for green secondary Battery》.
Chuan-Zheng Yang, Yu-Wan Lou，jian, Xiao-Hua Zhang, Bao-Jia Xie, Xia (2022) 《Materials and Working Mechanisms of Secondary Batteries》.
Chuan-Zheng Yang, Yuwan Lou, Jian Zhang, Xiaohua Xie, Baojia Xia (2023) Materials and Working Mechanisms of Secondary Batteries.
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2023-08-25
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