Adsorption and Kinetic Study of NI (II) Ions from Aqueous Solution using Natural Syrian Zeolite

Ibrahim Raheb

Authors

Ibrahim Raheb

adsorption, zeolite, Ni(II) ions

Abstract

Adsorption of Ni(II) ions from aqueous solution using natural Syrian zeolite has been studied. Batch shaking adsorption experiments were performed in order to determined the effects of contact time, pH and initial concentration on removal process. The experimental equilibrium data were tested for the Langmuir and Freundlish isotherms. It was determined that removal of Ni(II) ions was well fitted by pseudo-first order kinetic model. The adsorption involves a film diffusion, an intra-particle diffusion and a chemical ion-exchange between Na + ions of adsorbent and the Ni 2+ ions. The adsorption is endothermic and spontaneous process under studied conditions.

Downloads

How to Cite

Adsorption and Kinetic Study of NI (II) Ions from Aqueous Solution using Natural Syrian Zeolite. (2015). Global Journal of Science Frontier Research, 15(50), 21-25. https://journalofscience.org/index.php/GJSFR/article/view/

Download Citation

References

M. Pansini, C. Colella, M. De Gennaro (1991) Chromium removal from water by ion exchange using zeolite. 83(1-3), 145-157. https://doi.org/10.1016/0011-9164(91)85091-8

J. Vassilis, Maria Inglezakis, Helen Grigoropovlou (2004) Ion exchange studies on natural and modified zeolites and the concept of exchange site accessibility. 275, 570-576.

Djordje Nevenka Rajic, Mina Jovanovic, Matgas Natsa Zabukovec Logar, Venceslav Kavcic (2010) Removal of nickel(II) ions from aqueous solutions using the natural clinoptilolite and preparation of nano-NiO on the exhausted clinoptilolite.

Sousa.F.W, Oliveria.A.C, Riberio.J.P, Rosa.M.F, Keukeleire.D, Nascimento.R.E (2010) Green coconut shells applied as adsorbent for removal of toxic metal ions using fixed-bed column technology. 91(8), 1634-1640. https://doi.org/10.1016/j.jenvman.2010.02.011

Ritu Ambashta, Mika Sillanpää (2010) Water purification using magnetic assistance : a review, J.Hazard. 180(1-3), 38-49. https://doi.org/10.1016/j.jhazmat.2010.04.105

A. Shalback, Raheb Kruchinina (2010) Removal of colors for aqueous reactive dyes solutions by coagulation - flocculation process.

Vassilis Inglezakis (2005) The concept of capacity in zeolite ion-exchange systems., J. of Colloid and Inter. 281, 68-79.

Mehdi Alireza Nezamadeh-Ejhieh (2013) Effective of removal of Ni(II) from aqueous solutions by modification of nano particles of clinopfilolite with dimethyglyoxime.

Ibrahem Raheb, Husam Al-dien Kawass (2005) Characterization of Syrian ores containing zeolite from om'ozen area., Tishreen Univers . J. for Studies and Scientific Sesearch. 27, 69-78.

Mehmet Emin, Argun (2008) Use of clinoptilolite for the removal of nickel ions from water: kinetics and thermodynamic, J. of Hazard. 150, 587-595.

yu. Zhang.H, Chen.L, Jing.Y (2010) Study of 63Ni adsorption on NKF-6 zeolite. 101(12), 1061-1069. https://doi.org/10.1016/j.jenvrad.2010.08.009

Nibou.D, Markatel.H, Amokrane.S, Barkar.M, Trari.M (2010) Adsorption of Zn2+ ions onto NaA and NaX zeolites: Kinetic, equilibrium and thermodynamic studies. 173, 637-646.

Gupta.S.S, Bhattacharya.K.G (2006) Adsorption of Ni(II) on clays., J.Colloid. Inter. 295, 21-32.

Ibrahim, Jamal Hegazy (2010) Application of zeolite prepared from Egyption kaolin for the removal of heavy metals., J.Hazard. 182, 842-847.

Dal Basco.S.M, Jimenez.R.S, Carvalho.W.A (2005) Removal of toxic metals from wastewater by Brazilian natural scolecite. 281, 424-431.

Coonly.E.L, Booker.A, Shallcross.D, Stevens.G.W (1999) Ammonia Removal from Wastewaters Using Natural Australian Zeolite. II. Pilot-Scale Study Using Continuous Packed Column Process. 34(14), 2741-2760. https://doi.org/10.1081/ss-100100802

Mehmet Argun (2008) Use of clinoptilolite for the removal of nickel ions from water: Kinetics and thermodynamics. 150(3), 587-595. https://doi.org/10.1016/j.jhazmat.2007.05.008

Yavuz.O, Altunkaynak.Y, Guzel.F (2003) Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite. 37(4), 948-952. https://doi.org/10.1016/s0043-1354(02)00409-8