Abstract

The Complexes of Cu(II), Ni(II)), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) with Methyl 3-[(E,E)-3-phenylprop-2- enylidene]dithiocarbazate have been synthesized and characterized by elemental analysis, molar conductance, magnetic susceptibility, FT-IR, UV-Visible spectroscopy. The Schiff bases in every case behaved as bidentate, uninegative ligands. The complexes of Cu(II), Co(II) and Fe(III) are paramagnetic while all other complexes are diamagnetic. The complexes [Cu(C11H11N2S2)2] and [Ni(C11H11N2S2)2] had, square planar structures with two ligands satisfying the four steriochemical sites, where the complexes [Zn(C11H11N2S2)2] and [Cd(C11H11N2S2)2] were tetrahedral and the complexes [Sn(C11H11N2S2)2(H2O)2], [Co(C11H11N2S2)2(H2O)2], [Sb(C11H11N2S2)2(NO3) (H2O)] and [Fe(C11H11N2S2)2(NO3)(H2O)] were octahedral in geometry. The metal complexes have been screened for their antibacterial activity.

How to Cite
SHAKILA KHAN, Sultana. Synthesis, Characterization and Biological Activities of Cu(II), Ni(II), Zn(II), Cd(II), Sn(II), Co(II), Sb(III) and Fe(III) Complexes with Schiff base Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate. Global Journal of Science Frontier Research, [S.l.], sep. 2013. ISSN 2249-4626. Available at: <https://journalofscience.org/index.php/GJSFR/article/view/940>. Date accessed: 25 jan. 2022.